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§177.2410 用于模制品的酚醛树脂(Phenolic resins in molded articles)

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放大字体  缩小字体 2011-10-13 14:57:34  来源:GPO  浏览次数:2698
核心提示:酚醛树脂由本节(a)(1)中所列的一种或多种酚类,与本节(a)(2)中所列的一种或多种醛类反应而成,其中可用苯胺和/或脱水甲醛苯胺。在酚醛树脂生产中所加的辅料,或加入后能赋予所希望的工艺或物理性质的辅料,包括石棉纤维、氢氧化钡、硬脂酸钙、炭黑、硅藻土等。本节(c)规定了酚醛树脂的浸提物限量。
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备注 酚醛树脂由本节(a)(1)中所列的一种或多种酚类,与本节(a)(2)中所列的一种或多种醛类反应而成,其中可用苯胺和/或脱水甲醛苯胺。在酚醛树脂生产中所加的辅料,或加入后能赋予所希望的工艺或物理性质的辅料,包括石棉纤维、氢氧化钡、硬脂酸钙、炭黑、硅藻土等。本节(c)规定了酚醛树脂的浸提物限量。

     §177.2410 Phenolic resins in molded articles.

     Phenolic resins identified in this section may be safely used as the food-contact surface of molded articles intended for repeated use in contact with nonacid food (pH above 5.0), in accordance with the following prescribed conditions:

  (a) For the purpose of this section, the phenolic resins are those produced when one or more of the phenols listed in paragraph (a)(1) of this section are made to react with one or more of the aldehydes listed in paragraph (a)(2) of this section, with or without aniline and/or anhydro-formaldehyde aniline (hexahydro-1, 3,5-triphenyl-s-triazine):

  (1) Phenols:

  p-tert-Amylphenol.

  p-tert-Butylphenol.

  o-, m-, and p-Cresol.

  p-Octylphenol.

  Phenol.

  o- and p-Phenylethylphenol mixture produced when phenol is made to react with styrene in the presence of sulfuric acid catalyst.

  (2) Aldehydes:

  Acetaldehyde.

  Formaldehyde.

  Paraldehyde.

  (b) Optional adjuvant substances employed in the production of the phenolic resins or added thereto to impart desired technical or physical properties include the following:

Asbesto  fiber  
Barium hydroxides  For use as catalyst.
Calcium stearate  For use as lubricant.
Carbon black (channel process)  
Diatomaceous earth  
Glass fiber  
Hexamethylenetetramine  For use as curing agent.
Mica  
Oxalic acid  For use as catalyst.
Zinc stearate  For use as lubricant.
Code of Federal Regulations 341


      (c) The finished food-contact article, when extracted with distilled water at reflux temperature for 2 hours, using a volume-to-surface ratio of 2 milliliters of distilled water per square inch of surface tested, shall meet the following extractives limitations:

  (1) Total extractives not to exceed 0.15 milligram per square inch of food-contact surface.

  (2) Extracted phenol not to exceed 0.005 milligram per square inch of food-contact surface.

  (3) No extracted aniline when tested by a spectrophotometric method sensitive to 0.006 milligram of aniline per-square inch of food-contact surface.

  (d) In accordance with good manufacturing practice, finished molded articles containing the phenolic resins shall be thoroughly cleansed prior to their first use in contact with food.

 地区: 美国 
 标签: 限量 辅料 
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